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The intrinsic corrosion behavior of the aluminum current collector used in LIB was studied by coating thin films of PEDOT-nanosphere (NSP)/MWNT hybrids onto the Al surface. The coatings ensured fairly effective protection against pitting corrosion by co-operative electrostatic repulsion of PEDOT-NSP and COOH groups on MWNT against pit-causing anions.

Graphene oxide being an atomically thin sheet of carbon laden with oxygen functional groups effectively inhibits pitting corrosion of Al current collector in LIB by a simple, yet effective mechanism when coated on the Al surface.